I guess it's just second nature for us Canadians that were licensed before Canada adopted the Metric system... Don't even have to think anymore, the conversion is almost automatic. 100km = 60miles, 80=50, 60=40, 50=30, these aren't the numbers you'd get on a calculator, but if you look at a bilingual speedo, they're not more than a mile or two off - probably close enough to make no difference...
I remember when we first switched over, you could get sticker sets for those that had cars marked only in MPH. They had every multiple of 10 up to 180 or so, but most people I remember only put the ones corresponding to certain speed zones on : 100,80,60,50.
I'll admit to forgetting occasionally though. There have been a few times when I've been 'south of 49' on I81 and thought that traffic was moving REALLY fast for 65, before realizing I was doing 65kph rather than 65mph... About 25mph too slow.
Jamie